危险品货物运输范围包括危险货物第2类、第3类、第4类、第5类、第6类、第8类、第9类（具体如下）。
第2类：气体 ，包括：氩气、氧气、压缩空气、氮气、氢气、乙炔、二氧化碳、天然气、煤气等各种气体。
第3类：易燃液体，包括汽油、柴油、煤油、苯类、醇类、油漆等。
第4类：可燃性物质，包括安全火柴、硝纤象牙、金属粉末、磷、硫黄等自燃性物质，活性炭、硫化钠、金属催化剂等与水反应的可燃性物质，碳化物、镁、钡、碱土金属合金等。
第5类：氧化剂和有机过氧化物，包括氧化剂、含有过氧基的无机物、有机过氧化物等。
第6类：毒害品和感染性物品，包括毒害品和感染性物品。
第8类：酸碱性腐蚀品，包括硫酸、硝酸、盐酸、氢氧化钠、碱类等几百种化工品。
甲类、剧毒，防火、防热、防水。储存阴凉地方，禁止泄漏。
毒鼠强等5种禁用剧毒化学品任何人,任何情况下禁止做,不能做,不许做,不许买，不许卖，不许存,不许用 ,否则要触犯刑法125条第二款. MDI,TDI,三氯氧磷,红矾钠等 是其他一般剧毒化学品.按危险化学品管理条例，生产要许可证，使用要备案,规定做,限制做, 限制买，限制卖，限制存,限制用,否则触犯危险化学品管理条例,要限期整改,拒不整改的要按行政处罚法,罚款. 中华人民共和国最高人民法院祝二军处长博士"<<关于办理非法制造、买卖、运输、储存毒鼠强等禁用剧毒化学品刑事案件具体应用法律若干问题的解释>的理解与适用> 道出了立法的本意.但下面公安部门把335种剧毒化学品,如生产大量用的液氯 三氯氧磷 红矾钠 TDI等化工原料偶尔触犯危化管理条例的都往刑法125条第二款套,先来一个取保候审.冤屈,影响生产不说,浪费司法资源呀!! EN
**** MATERIAL SAFETY DATA SHEET ****
Tolylene-2,4-diisocyanate, tech., 80%
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: Tolylene-2,4-diisocyanate, tech., 80%
Catalog Numbers:
20250-0000, 20250-0010, 20250-2500
Synonyms:
4-Methyl-1,3-phenylene diisocyanate; TDI
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
| 584-84-9 |Tolylene-2,4-diisocyanate | tech., 8 | 209-544-5 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Hazard Symbols: T+
Risk Phrases: 26 36/37/38 40 42/43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation. Irritating to eyes, respiratory system and
skin. Limited evidence of a carcinogenic effect. May cause
sensitization by inhalation and skin contact. Harmful to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.Moisture sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which
increases the flow of tears).
Skin:
Causes severe skin irritation. May be harmful if absorbed through
the skin. May cause sensitization by skin contact.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May cause severe irritation of
the respiratory tract with sore throat, coughing, shortness of
breath and delayed lung edema. Toxic if inhaled.
Chronic:
Repeated exposure may cause allergic respiratory reaction (asthma).
May cause allergic skin reaction in some individuals. Limited
evidence of a carcinogenic effect.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a dry area. Keep
refrigerated. (Store below 4°C/39°F.) Store under nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless to light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 0.04 mbar @ 20 deg C
Viscosity: Not available.
Boiling Point: 115 - 120 deg C @ 10mmHg
Freezing/Melting Point: 12.5 - 13.5 deg C
Autoignition Temperature: > 620 deg C (> 1,148.00 deg F)
Flash Point: 127 deg C ( 260.60 deg F)
Explosion Limits, lower: 0.9 vol %
Explosion Limits, upper: 9.5 vol %
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.220
Molecular Formula: C9H6N2O2
Molecular Weight: 174.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
High temperatures, incompatible materials, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, strong bases, alcohols, amines.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 584-84-9: CZ6300000
LD50/LC50:
CAS# 584-84-9: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, skin: 500 mg/24H Moderate; Inhalation, mouse: LC50 = 10
ppm/4H; Inhalation, rabbit: LC50 = 11 ppm/4H; Inhalation, rat: LC50 =
14 ppm/4H; Oral, rat: LD50 = 5800 mg/kg; Skin, rabbit: LD50 = >16
mL/kg.
Not available.
Carcinogenicity:
Tolylene-2,4-diisocyanate -
NIOSH: potential occupational carcinogen
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50: 164 mg/l; 24h; .
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOLUENE DIISOCYANATE
Hazard Class: 6.1
UN Number: 2078
Packing Group: II
IMO
Shipping Name: TOLUENE DIISOCYANATE
Hazard Class: 6.1
UN Number: 2078
Packing Group: II
RID/ADR
Shipping Name: TOLUENE DIISOCYANATE
Hazard Class: 6.1
UN Number: 2078
Packing group: II
USA RQ:CAS# 584-84-9: 100 lb final RQ (Listed under Toluene diisocyanate); 45.4 kg final RQ (Listed un
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26 Very toxic by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 40 Limited evidence of a carcinogenic effect.
R 42/43 May cause sensitization by inhalation and
skin contact.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 584-84-9: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 584-84-9 is listed on Canada's DSL List.
CAS# 584-84-9 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 584-84-9: OEL-ARAB Republic of Egypt:TWA 0.02 ppm (0.14 mg/m3)
OEL-BELGIUM:TWA 0.005 ppm (0.036 mg/m3);STEL 0.02 ppm
OEL-CZECHOSLOVAKIA:TWA 0.07 mg/m3;STEL 0.14 mg/m3
OEL-DENMARK:TWA 0.005 ppm (0.035 mg/m3);Carcinoge
OEL-FRANCE:TWA 0.01 ppm (0.08 mg/m3);STEL 0.02 pp (0.16 mg/m3)
OEL-GERMANY:TWA 0.01 ppm (0.07 mg/m3)
OEL-HUNGARY:STEL 0.04 mg/m3
OEL-JAPAN:TWA 0.02 ppm (0.14 mg/m3)
OEL-THE NETHERLANDS:TWA 0.02 ppm (0.14 mg/m3);Ski
OEL-THE PHILIPPINES:TWA 0.02 ppm (0.14 mg/m3)
OEL-RUSSIA:STEL 0.05 mg/m3
OEL-SWEDEN:TWA 0.005 ppm (0.04 mg/m3);STEL 0.01 ppm (0.07 mg/m3)
OEL-SWITZERLAND:TWA 0.005 ppm (0.04 mg/m3);STEL 0.01 ppm
OEL-THAILAND:TWA 0.02 ppm (0.14 mg/m3)
OEL-TURKEY:TWA 0.02 ppm (0.14 mg/m3)
OEL-UNITED KINGDOM:TWA 0.02 mg/m3;STEL 0.07 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 584-84-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/16/1996 Revision #1 Date: 8/05/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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